Covalent Surface Chemistry of Single‐Walled Carbon Nanotubes
Identifieur interne : 003010 ( Main/Exploration ); précédent : 003009; suivant : 003011Covalent Surface Chemistry of Single‐Walled Carbon Nanotubes
Auteurs : S. Banerjee [États-Unis] ; T. Hemraj-Benny [États-Unis] ; S. Wong [États-Unis]Source :
- Advanced Materials [ 0935-9648 ] ; 2005-01-06.
English descriptors
- Teeft :
- Adduct, American chemical society, Banerjee, Carbon nanotubes, Carbon nanotubes figure, Carboxylic, Carboxylic acids, Chem, Chemical functionalization, Chemical moieties, Copyright, Covalent, Covalent sidewall functionalization, Defect, Defect sites, Electron transfer, Electronic structure, Fermi level, Fullerene, Functional groups, Functionalization, Functionalized, Gmbh, Haddon, Hamon, Height image, Height images, Itkis, January, Kgaa, Lett, Margrave, Mater, Moiety, Nano, Nano lett, Nanotube, Nanotube sidewalls, Nanotube surface, Nanotube surfaces, Oxygenated, Oxygenated functionalities, Phys, Prato, Pyramidalization, Quantum dots, Review banerjee, Semiconducting nanotubes, Sidewall, Sidewall functionalization, Smalley, State university, Stony brook, Swnt, Swnt sidewalls, Swnt surfaces, Swnts, Verlag, Verlag gmbh, Weinheim, Wong.
Abstract
In this review article, we explore covalent chemical strategies for the functionalization of carbon‐nanotube surfaces. In recent years, nanotubes have been treated as chemical reagents (be it inorganic or organic) in their own right. Indeed, from their inherent structure, one can view nanotubes as sterically bulky, π‐conjugated ligands, or conversely as electron‐deficient alkenes. Hence, herein we seek to understand, from a structural perspective, the breadth and types of reactions single‐walled nanotubes (SWNTs) can undergo in solution phase, not only at the ends and defect sites but also along the sidewalls. Controllable chemical functionalization suggests that the unique electronic and mechanical properties of SWNTs can be tailored in a determinable manner. Moreover, prevailing themes in nanotube functionalization have been involved with dissolution of tubes.
Single‐walled carbon nanotubes are now considered chemical reagents in their own right. Understanding the reactivity of carbon nanotubes will lead to manipulation of their unique properties in a predictable manner. In this review, reactions leading to functionalization of carbon nanotubes at their ends, at defect sites, and along their sidewalls are discussed with the goal of creating functional nanomaterials with possible device applications and of generating nanoscale hierarchical architectures and assemblies.
Url:
DOI: 10.1002/adma.200401340
Affiliations:
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Understanding the reactivity of carbon nanotubes will lead to manipulation of their unique properties in a predictable manner. In this review, reactions leading to functionalization of carbon nanotubes at their ends, at defect sites, and along their sidewalls are discussed with the goal of creating functional nanomaterials with possible device applications and of generating nanoscale hierarchical architectures and assemblies.</div></front></TEI><affiliations><list><country><li>États-Unis</li></country><region><li>État de New York</li></region><settlement><li>New York</li></settlement><orgName><li>Université Columbia</li></orgName></list><tree><country name="États-Unis"><noRegion><name sortKey="Banerjee, S" sort="Banerjee, S" uniqKey="Banerjee S" first="S." last="Banerjee">S. Banerjee</name></noRegion><name sortKey="Banerjee, S" sort="Banerjee, S" uniqKey="Banerjee S" first="S." last="Banerjee">S. 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